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Seema
22 Jan 2017

Carry out the following conversions:

i. Toluene to benzyl alcohol

ii. Bromobenzene to benzene

iii. Propan-2-ol to 1-bromopropane

or
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Reaction Ch3mgbr Result Addition Hbr 1 Phenyl Propene Reaction Alkyl Chlorides Bromides Sodium Iodide Dry Acetone Form Alkyl Iodide KnownFollowing Compounds Highest Boiling Point Following Halides Undergoes Sn2 Reaction Faster Use Following Information Answer Next Question Correct Order Increasing Reactivity Given Compounds SFollowing Alternatives Use Dichloromethane Following Polyhalogen Compounds Used Antiseptic Use Following Information Answer Next Question Chlorofluorocarbon Compounds Collectively Called FreoPhosgene Common NameUse Following Information Answer Next Question Information Alternative Completes Given Equation Following Alkyl Halides Produced Swarts Reaction Correct Order Increasing Density N Propyl HalidesStructure Iupac Name 4 Chloro 4 Methylpent 2 Ene Many Mono Chloro Structural Isomers Expected Formed Free Radical Mono Chlorination Use Following Information Answer Next Question Toluene Allowed React Br2 Presence Fe Results FormatiUse Following Information Answer 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Determining Rightful Owner Land Policemen B District Collector C Land Records ChowkidarsMaintaining Law Order District Important Responsibility District Collector B Police Officer C PanchaFair Reserve Seats Women Sc St Gram Panchayat System Enables People Run Local Government Rural Areas Zila Parishad B Block Samiti C Pachayati Raj Solution Koh Hydrolyses Ch3chclch2ch3 Ch3ch2ch2cl One Easily Hydrolysed State Oneuseeach Ddt Iodoform Ii Compound Following Couples React Faster Sn2 Displacement 1 BromopeWrite Iupac Name Given Compound Classify Following Compounds Allylic Benzylic Vinylic Halides Boiling Point N Pentyl Chloride Higher Neo Pentyl Chloride Explain Ethyl Nitrile Formed Given Reaction Give One Step Reaction Preparation Propyl Iodide Propyl Chloride Giving Reasons Arrange Following Alcohols Decreasing Order Reactivity Towards Hi Form Iodo Alkanes Name Products Formed Chlorination Methane Presence Heat B Drawback Reaction Chlorination Chlorobenzene Presence Fecl3 Give Mixture 1 4 1 2 Dichlorobenzene B Electrophilic SubstGiven Compounds Compound Reactive Towards Hydrolysis Form Product Inverted Configuration Give ReasonMolecular Formula Compound C6h7n Compound Treatment Sodium Nitrite Followed Cuprous Chloride Forms CCarry Following Conversions Toluene Benzyl Alcohol Ii Bromobenzene Benzene Iii Propan 2 Ol 1 BromoprReaction Used Preparation Flouromethane Bromomethane Beginning Toulene Write Reactions Involved Preparation P Chloro Toulene B 1 Chloro 1 Phenyl MethaneP Dichloro Benzene Higher Melting Point Lower Solubility Isomers Bromobenzene Bromoethane Less Reactive Towards Nucleophilic Substitution Give Two Reasons Draw Structures Following Compounds 1 Chloro 5 Methyl Hexan 2 One Ii 2 2 Bromophenyl Ethanal B AccouBond Enthalpy C Cl Bond Ch3cl 351 Kj Mol 1 Compared 293 Kj Mol 1 C Br Bond Ch3br Increasing Order Bond Lengths Following Compounds Give Products Formed 2 Chlorobutane Treated Alcoholic Koh B Major Product Reaction Given Compounds Ii Iii Reactivity Haloarene Increase Towards Naoh H Among Given Hydrides Hydride React Readily Ethene Hcl Hi Hbr Formation Products Reactants Requires Proper Orientation Reactant Molecules Explain Statement CitingProduct Products Obtained Chlorobenzene Reacts Propyl Chloride Presence Anhydrous Alcl3 Also Write MComplete Following Reaction Iodination Benzene Carried Presence Hno3 Major Product Formed Compound Reacts Ch3ch2o Na B Given Dichloro Benzenes Highest Melting Point Different Products Obtained Ethyl Chloride Reacts Silver Nitrite Potassium Nitrite Organic Compound Molecular Formula C7h7cl Reaction Alcoholic Agno2 Gives Compound Reduction Sn Hcl GFollowing Compounds React Water Forming Product Inverted Configuration Draw Structure Given Compounds 1 Bromo 2 Phenyl Ethane 4 Tert Butyl 3 Iodo Heptane B Order ReactivitWrite Iupac Name Given Compound Ethane Obtained Bromoethane Using Organo Metallic Compounds Draw Structures Mono Chloro Structural Isomers Expected Formed Free Radical Mono Chlorination Write One Step Method Preparation 2 4 6 Trinitrophenol 2 4 6 Trinitro Chlorobenzene B Explain EffectOrganic Compound Molecular Formula C6h7n Treatment Nano2 Hcl 273 278 K Gives Intermediate B Reacts CMechanism Involved Preparation Mixture Butan 2 Ol Butan 2 Ol 2 Bromobutane Vinyl Chloride HydrolysedAccount Following Observations Tert Butyl Chloride Reacts Aqueous Sodium Hydroxide Solution Sn1 MechMethod Preparation 1 1 Dichloro 1 Phenylethane Ethyl Benzene Complete Given Reaction B Product Obtained Aq Koh Replaced Alcoholic Koh Part Explain Chloroethane Soluble Water Benzene Give Reasons Draw Structure Products Determine Configurations Respect Reactants Given Reactions B C Choose Correct Option Regarding Chloronitrobenzene P Chloronitrobenzene B Following Names Correctly Match Reactions Iupac Name Following CompoundComplete Following Reaction Gem Dihalide 1 1 Dichloroethane Hydrolysis Aq Koh Gives Compound X Upon Treatment Reagent R Forms YeFollowing Compounds Maximum Boiling Point Present Asha Age Years 2 Square Daughter Nisha Age Nisha Grows Mother Present Age Asha Age Would OneReaction Alkyl Chlorides Bromides Sodium Iodide Dry Acetone Form Alkyl Iodide KnownFollowing Halides Undergoes Sn2 Reaction Faster Use Following Information Answer Next Question Correct Order Increasing Reactivity Given Compounds SUse Following Information Answer Next Question Chlorofluorocarbon Compounds Collectively Called FreoPhosgene Common NameUse Following Information Answer Next Question Information Alternative Completes Given Equation Following Alkyl Halides Produced Swarts Reaction Correct Order Increasing Density N Propyl HalidesStructure Iupac Name 4 Chloro 4 Methylpent 2 Ene Use Following Information Answer Next Question Addition Br2 Ccl4 Ethene Results Formation Compound XMany Mono Chloro Structural Isomers Expected Formed Free Radical Mono Chlorination Use Following Information Answer Next Question Toluene Allowed React Br2 Presence Fe Results FormatiBond Enthalpy C Cl Bond Ch3cl 351 Kj Mol 1 Compared 293 Kj Mol 1 C Br Bond Ch3br Write Iupac Name Given Compound Method Preparation 1 1 Dichloro 1 Phenylethane Ethyl Benzene Among Given Hydrides Hydride React Readily Ethene Hcl Hi Hbr Complete Following Reaction Among Ethane Bromoethane Compound Higher Boiling Point Methyl Iodide Turns Violet Presence Light Observed Case Methyl Chloride Following Compounds React Water Forming Product Inverted Configuration Draw Possible Enantiomer 2 3 Dimethyl Pentane Ethane Obtained Bromoethane Using Organo Metallic Compounds Chloroform Stored Dark Coloured Bottles Brown Colour Bromine Gets Discharged Br2 Added Ethene Presence Ccl4 Role Anhydrous Zncl2 Given Reaction Although Haloarenes Undergo Electrophilic Substitution Reaction Occurs Slowly Compared Benzene Write Name Reaction Used Obtaining Diphenyl Chlorobenzene Iodination Benzene Carried Presence Hno3 Given Dichloro Benzenes Highest Melting Point Classify Following Molecule Optically Active Inactive Complete ReactionWrite Possible Structural Isomers Compound X C F Bond Ch3f Polar Covalent Bond Justify Statement Many Mono Chloro Structural Isomers Expected Formed Mono Chlorination 2 2 Dimethylbutane Chloroethane Soluble Water Benzene Give Reasons Iodobenzene Prepared Aniline Method Preparation 1 Bromopropane Propene Mechanism Involved Preparation Mixture Butan 2 Ol Butan 2 Ol 2 Bromobutane Vinyl Chloride Hydrolysed Slower Pace Ethyl Chloride Product Products Obtained Chlorobenzene Reacts Propyl Chloride Presence Anhydrous Alcl3 Also Write MCh3ch2o Na Different Products Obtained Ethyl Chloride Reacts Silver Nitrite Potassium Nitrite Draw Structure Given Compounds 1 Bromo 2 Phenyl Ethane 4 Tert Butyl 3 Iodo HeptaneOrder Reactivities 1 2 3 Alcohols Given Reaction R Oh Hi R H2o R Alkyl Group Chloroethane Prepared Alcohols Replacement Oh Group Chlorine Atom Chlorobenzene Cannot Prepared PhenChlorobenzotrichloride Obtained Benzyl Chloride Write One Step Method Preparation 2 4 6 Trinitrophenol 2 4 6 Trinitro Chlorobenzene Explain Effect Reactivity Chlorobenzene Nitro Group Present Meta Position Instead Para Position Tert Butyl Chloride Reacts Aqueous Sodium Hydroxide Solution Sn1 Mechanism N Butyl Chloride Reacts SBenzyl Chloride Undergoes Hydrolysis Faster Rate Chlorobenzene Complete Given Reaction Product Obtained Aq Koh Replaced Alcoholic Koh Part Explain Draw Structural Isomers C4h9br Explain Isomer Undergo Elimination Reaction Readily Chlorobenzene Reacts Koh Slower Rate Compared Chloroethane Giving Reasons Arrange Given Compounds Decreasing Order Boiling Points Butene N Butyl IodideEthanoic Acid Bromomethane2 Propanol BromopropaneAniline BromobenzeneEthanol FlouroethaneHydrocarbon Exhibits Maximum Three Structural Isomers Straight Chain Isomer Reacting Chlorine PresenOrganic Compound Molecular Formula C6h7n Treatment Nano2 Hcl 273 278 K Gives Intermediate B Reacts CWrite Iupac Name Given Compound Classify Following Compounds Allylic Benzylic Vinylic Halides Boiling Point N Pentyl Chloride Higher Neo Pentyl Chloride Explain Ethyl Nitrile Formed Given Reaction Give One Step Reaction Preparation Propyl Iodide Propyl Chloride Indicate Chiral Carbon 3 Bromopent 1 Ene Reaction Used Preparation Flouromethane Bromomethane Increasing Order Bond Lengths Following Compounds Giving Reasons Arrange Following Alcohols Decreasing Order Reactivity Towards Hi Form Iodo Alkanes Name Products Formed Chlorination Methane Presence Heat Drawback Reaction P Chloro Toulene1 Chloro 1 Phenyl MethaneP Dichloro Benzene Higher Melting Point Lower Solubility Isomers Give Products Formed 2 Chlorobutane Treated Alcoholic Koh Major Product Reaction Chloroform Stored Closed Dark Coloured Bottles Give One Major Use Chloroform Chlorination Chlorobenzene Presence Fecl3 Give Mixture 1 4 1 2 Dichlorobenzene Electrophilic Substitution Reactions Haloarenes Occur Slowly Compared Reactions Benzene Given Compounds Ii Iii Reactivity Haloarene Increase Towards Naoh H Given Compounds Compound Reactive Towards Hydrolysis Form Product Inverted Configuration Give ReasonBromobenzene Bromoethane Less Reactive Towards Nucleophilic Substitution Give Two Reasons Giving Mechanism Explain Following Compounds Undergo Sn2 Mechanism Faster Rate Explain Allylic Halides Show High Reactivity Towards Sn1 Reaction DiphenylTolueneP Chloro AcetophenoneMolecular Formula Compound C6h7n Compound Treatment Sodium Nitrite Followed Cuprous Chloride Forms CCarry Following Conversions Toluene Benzyl Alcohol Ii Bromobenzene Benzene Iii Propan 2 Ol 1 BromoprIdentify X Z Following Reactions Following Structural Isomers Butyl Chloride Highest Boiling Point Product Formed Treating Propene Bromine Room TemperatureUse Following Information Answer Next Question 2 Bromopropane Reacts Koh Give Compound Treated AlcohMajor Product Substitution Reaction One Mole Bromine Presence Febr3 BenzeneGeneral Form Wurtz Reaction RepresentedUse Following Information Answer Next Question Reaction Involving Replacement Diazonium Group ChloroUse Following Information Answer Next Two Questions According Markovnikov Rule Hydrogen Halide AddedResult Markovnikov Addition Hbr 1 Phenyl Propene Major Product Following ReactionTwo Chemicals X Involved Following Series Reactions XFollowing Compounds Produce Butan 2 Ol Reaction Ch3mgbr Result Addition Hbr 1 Phenyl Propene Use Following Information Answer Question Used Solvent Fats Alkaloids Etc Inhaling Vapours Cause Ii Use Following Information Answer Question Polyhalogen Compound Used Propellant Aerosols Also Used MeUse Following Information Answer Question Polyhalogen Compound Uses X Ccl4 Antiseptic Chi3 Ii Metal Following Structures Correctly Represents Pesticide Named Ddt Following Statements Incorrect Compound X Reagent Dipole Moment ShownAerosol Depletes Ozone Layer Write Iupac Name Following Compound Give Reasons Following Ethyl Iodide Undergoes Sn2 Reaction Faster Ethyl Bromide Ii 2 Butanol OpticalWrite Iupac NameHappens Ch3 Br Treated Kcn Chlorobenzene Extremely Less Reactive Towards Nucleophilic Substitution Reaction Give Two Reasons Write Iupac NameHappens Ethyl Chloride Treated Aqueous Koh P Dichlorobenzene Higher P Isomers B Butan 2 Ol Optically Inactive Write Iupac Name Ch3 2 Ch Ch Cl Ch3 Compound Flowing Pair Undergoes Faster Sn1 Reaction Account Following C Cl Bond Length Chlorobenzene Shorter Ch3 Cl Ii Chloroform Stored Closed Dark BroGive Iupac Name Following Compound Although Chlorine Electron Withdrawing Group Yet Ortho Para Directing Electrophilic Aromatic SubstitGive Iupac Name Following Compound Although Chlorine Electron Withdrawing Group Yet Ortho Para Directing Electrophilic Aromatic SubstitGive Iupac Name Following Compound Although Chlorine Electron Withdrawing Group Yet Ortho Para Directing Electrophilic Aromatic SubstitDraw Structure Major Monohalo Product Following Reactions Ii Alkyl Halide Following Pair Chiral Undergoes Faster Sn2 Reaction Ii Sn1 Sn2 Reaction Occurs Inversi Write Mechanism Following Reaction Ch3ch2oh Hbr Ch3ch2br H2o B Write Equation Involved Reimer Tiema Alkyl Halide Following Pair Chiral Undergoes Faster Sn2 Reaction Ii Sn1 Sn2 Reaction Occurs InversiDraw Structure Major Monohalo Product Following Reactions Ii Alkyl Halide Following Pair Chiral Undergoes Faster Sn2 Reaction Ii Sn1 Sn2 Reaction Occurs InversiDraw Structure Major Monohalo Product Following Reactions Ii Write Mechanism Following Reaction Ch3ch2oh Hbr Ch3ch2br H2o B Write Equation Involved Reimer TiemaIdentify Chiral Molecule Following Pair Write Mechanism Following Reaction Ch3ch2oh Hbrch3ch2br H2o Draw Structures Major Monohalo Products Following Reactions Ii B Halogen Compound Following Pairs RIdentify Chiral Molecule Following Pair Write Mechanism Following Reaction Ch3ch2oh Hbrch3ch2br H2o Draw Structures Major Monohalo Products Following Reactions Ii B Halogen Compound Following Pairs RWould Undergo Sn2 Reaction Faster Following Pair Give Reasons N Butyl Bromide Higher Boiling Point Butyl Bromide B Racemic Mixture Optically InactiveWould Undergo Sn2 Reaction Faster Following Pair Give Reasons N Butyl Bromide Higher Boiling Point Butyl Bromide B Racemic Mixture Optically InactiveWould Undergo Sn2 Reaction Faster Following Pair Give Reasons N Butyl Bromide Higher Boiling Point Butyl Bromide B Racemic Mixture Optically InactiveWould Undergo Sn1 Reaction Faster Following Pair Write Structure Major Product Following Reactions Give Reasons Following Phenol Acidic Ethanol Ii Boiling Point Ethanol Higher Comparison MethoxymethaWould Undergo Sn2 Reaction Faster Following Pair Ch3 Ch2 Br Ch3 Ch2 Alkyl Halides Insoluble Water B Butan 1 Ol Optically Inactive Butan 2 Ol Optically Active C AlthougPredict Products Following Reactions Ch3 Ch Ch2 Ii 3 H2o2 Oh B2h6 Ii C6h5 Oh Br2aq Iii Ch3ch2oh Cu 5Reactive Towards Sn1 Reaction Given Reasons C Cl Bond Length Chlorobenzene Shorter C Cl Bond Length Ch3 Cl Ii Dipole Moment ChloroWrite Structure Isomer Compound C4h9br Reactive Towards Sn1 Reaction Write Structure 1 Bromo 4 Chlorobut 2 Ene Following Compounds Given 2 Bromopentane 2 Bromo 2 Methylbutane 1 Bromopentane Write Compound ReactiWrite Structure 3 Bromo 2 Methylprop 1 Ene Example Benzylic Halide Following Compounds Given 2 Bromopentane 2 Bromo 2 Methylbutane 1 Bromopentane Write Compound ReactiChlorobenzene Benzyl Chloride One Gets Easily Hydrolysed Aqueous Naoh Define Ambident Nucleophile Example Ch3 3c Br Ch3 3 C One Reactive Towards Sn1 Ii Write Product Formed P Nitrochlorobenzene Heated AqueWrite One Stereochemical Difference Sn1 Sn2 Reactions Write Structures Main Compounds B Following Reactions Arrange Following Increasing Order Base Strength Gas Phase C2h5 3n C2h5nh2 C2h5 2nhMonochloro Derivative Pentane Chiral Write Name 1 1 1 Trichloro 2 2 Bis 4 Chlorophexyl Ethane Popularly Known One Following Reagents Acceptable Preparing Chloroalkanes Alcohols Socl2 Hcl Pcl5 Pcl 3Assertion Benzyl Bromide Kept Acetone Water Produces Benzyl Alcohol Reason Reaction Follows N2 MechaAssertion Boiling Point Alkyl Halide Decrease Order Ri Rbr Rcl Rf Reason Fluorine Electronegative AtGive Method Preparation Ethanoic Acid Propanoic Acid B Predict Product Formed Hoffmann Bromamide DegGiving Reasons Arrange Given Compounds Decreasing Order Boiling Points Undergo Sn1 Reaction Faster Oh Conversion Alkyl Halide Alcohol Aqueous Naoh Classified Dehydrohalogenation Reaction B Substitution Conversion Methyl Chloride Methyl Fluoride Known Finkeltein Reaction B Swarts Reaction C Williamson Write Chemical Reactions Chlorobenzene Respect Sulphonation B Acetylation C NitrationAction Following Ethyl Bromide Alcoholic Solutions Potassium Hydroxide Ii Moist Silver Oxide Iii SilRead Passage Given Answer Following Questions Sn1 Reaction Substitution Nucleophilic Unimolecular ReIdentify Following Reaction 2na Dryether 2 2 5 5 Tetramethylhexane 2nabr 2 Bromo 2 Methylbutane B L Compound Ethane B Propane C N Butane N PentaneDefine Racemic Mixture Give Iupac Name Explain Mechanism Alkaline Hydrolysis Tert Butyl Bromide Energy Profile Diagram Define Carbolic AcidChlorobenzene Prepared Aniline Chlorobenzene Converted Diphenyl Select Write Appropriate Answers Given Alternatives Preparation Alkyl Fluoride Alkyl Chloride PresenCorrect Iupac Name Given Compound Following Reagents Used Preparation Alkyl Fluorides Alkyl Chlorides Bromides Following Question Statement Assertion Followed Statement Reason Choose Correct Answer Following ChoReaction Leads Production Grignard Reagent Products Obtained Reaction Chlorobenzene Conc Hno3 Conc H2so4 Chemical Formula Poisonous Gas Obtained Oxidation Chloroform Following Alkyl Bromides Reactive Towards Sn2 Reaction Substitution Primary Alkyl Chloride Nucleophile Takes Place Step Substitution Tertiary Alkyl ChloridCorrect Order Reactivity Alkyl Halides Towards Nucleophilic Substitution Reactions Product Obtained Sn2 Reaction Asymmetric Compound Always